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Oxidation of organic compounds with pentavalent vanadium

Abstract:

Vanadium (V) only possesses oxidising properties in acid solutions. The main species present in these conditions is that cation VO2+, but this is protonated to a small extent to give the more powerfully oxidising species V(OH)23+.

Previous work in this laboratory has shown that vanadium (V) is a one-electron oxidising agent and is reduced by organic compounds to vanadium (IV) only. No vanadium (III) has yet been detected in any ...

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Department:
University of Oxford
Role:
Author


DOI:
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford


UUID:
uuid:2ea7b40d-7474-4fe2-b440-5e03da5e2087
Local pid:
polonsky:9:47
Source identifiers:
601870563
Deposit date:
2017-10-05
ARK identifier:

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