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Thesis

Development and application of bifunctional iminophosphorane organocatalysts

Abstract:

This thesis presents the development and application of bifunctional iminophosphorane (BIMP) organocatalysts, incorporating a triaryl-substituted iminophosphorane organosuperbase for organocatalytic enantioselective reactions.

Chapter 2 describes the design and synthesis of a new class of BIMP catalysts and its application in the first organocatalytic enantioselective sulfa-Michael reaction of alkyl thiols to unactivated β-substituted α,β-unsaturated esters. The conjugate adducts we...

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Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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Name:
China Scholarship Council Scholarship
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
UUID:
uuid:fa250f43-ab91-4aec-9fa3-f6ccdb444bb5
Deposit date:
2017-08-07

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