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Synthesis and reactivity of transition metal-group 13 complexes

Abstract:

The synthesis and reactivity of a number of mixed transition metal-aluminium and σ-alane complexes are detailed in this thesis.

Chapter III reports on the formation and structural characterisation of N,N'-chelated aluminium dihalide precursors featuring amidinate and guanidinate substituents. These precursors of the type RC(R'N)2AlX2 (R = iPr2N or Ph; R' = Cy or iPr or Dipp; X = hal), readily react wit...

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Institution:
University of Oxford
Research group:
Aldridge Group
Oxford college:
Queen's College, The
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory

Contributors

Role:
Supervisor
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Funding agency for:
Ian Martin Riddlestone
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
URN:
uuid:f253a2a5-cc6e-4978-86d9-5f3064dadc1b
Local pid:
ora:7026

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