Journal article
Photodissociation dynamics and the dissociation energy of vanadium monoxide,VO, investigated using velocity map imaging
- Abstract:
-
Velocity map imaging has been employed to study multi–photon fragmentation of vanadium monoxide (VO) via the C 4Σ– state. The fragmentation dynamics are interpreted in terms of a dissociation at the three–photon level, with the first photon weakly resonant with transitions to vibrational energy levels of the C 4Σ– state. The dissociation channels accessed are shown to depend strongly on the vibration level via which excitation takes place. Analysis of the evolution of the kinetic energy release spectrum with photon energy leads to a refined value for the dissociation energy of ground state VO of D0(VO) = 53126 ± 263 cm-1.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Version of record, pdf, 4.7MB, Terms of use)
-
(Preview, Version of record, pdf, 392.0KB, Terms of use)
-
- Publisher copy:
- 10.1039/c9cp02120e
Authors
- Publisher:
- Royal Society of Chemistry
- Journal:
- Physical Chemistry Chemical Physics More from this journal
- Volume:
- 21
- Pages:
- 15560-15567
- Publication date:
- 2019-06-24
- Acceptance date:
- 2019-06-24
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- Language:
-
English
- Pubs id:
-
pubs:1025035
- UUID:
-
uuid:e07e1c5a-e6c3-482f-a576-693ec43e5c37
- Local pid:
-
pubs:1025035
- Source identifiers:
-
1025035
- Deposit date:
-
2019-07-01
- ARK identifier:
Terms of use
- Copyright holder:
- the Owner Societies
- Copyright date:
- 2019
- Notes:
- © the Owner Societies 2019. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
- Licence:
- CC Attribution (CC BY)
If you are the owner of this record, you can report an update to it here: Report update to this record