Journal article
Copper-catalyzed synthesis of masked (hetero)aryl sulfinates
- Abstract:
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Catalysis using substoichiometric copper facilitates the synthesis of masked (hetero)aryl sulfinates under mild, base-free conditions from aryl iodides and the commercial sulfonylation reagent sodium 1-methyl 3-sulfinopropanoate (SMOPS). The development of a tert-butyl ester variant of the SMOPS reagent allowed the use of aryl bromide substrates. The sulfones thus generated can be unmasked and functionalized in situ to form a variety of sulfonyl-containing functional groups.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Preview, Version of record, pdf, 1.5MB, Terms of use)
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- Publisher copy:
- 10.1021/acs.orglett.3c03621
Authors
- Publisher:
- American Chemical Society
- Journal:
- Organic Letters More from this journal
- Volume:
- 26
- Issue:
- 14
- Pages:
- 2817-2820
- Publication date:
- 2024-01-08
- Acceptance date:
- 2023-12-29
- DOI:
- EISSN:
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1523-7052
- ISSN:
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1523-7060
- Pmid:
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38189248
- Language:
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English
- Keywords:
- Pubs id:
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1598743
- Local pid:
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pubs:1598743
- Deposit date:
-
2024-01-20
Terms of use
- Copyright holder:
- Merino et al.
- Copyright date:
- 2024
- Rights statement:
- © 2024 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0.
- Licence:
- CC Attribution (CC BY)
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