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Voltammetry of adsorbed species: Nonideal interactions leading to phase transitions

Abstract:

Phase transition behaviors are not uncommon in voltammetry owning to strong interactions on the surface. By coupling interfacial electrode kinetics with the Frumkin adsorption isotherm, the underlying physicochemical processes occurring in voltammetry-induced phase transition are studied via simulation herein. We report that phase-transition-like behavior is only observable in voltammetry under reversible electrode kinetics, which otherwise would lead to a “disconnection” from the Frumkin ads...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.jpcc.0c03791

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Publisher:
American Chemical Society
Journal:
Journal of Physical Chemistry C More from this journal
Volume:
124
Issue:
33
Pages:
18031-18044
Publication date:
2020-07-24
Acceptance date:
2020-07-22
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Language:
English
Keywords:
Pubs id:
1121014
Local pid:
pubs:1121014
Deposit date:
2020-07-25

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