Journal article
Voltammetry of adsorbed species: Nonideal interactions leading to phase transitions
- Abstract:
-
Phase transition behaviors are not uncommon in voltammetry owning to strong interactions on the surface. By coupling interfacial electrode kinetics with the Frumkin adsorption isotherm, the underlying physicochemical processes occurring in voltammetry-induced phase transition are studied via simulation herein. We report that phase-transition-like behavior is only observable in voltammetry under reversible electrode kinetics, which otherwise would lead to a “disconnection” from the Frumkin ads...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of Physical Chemistry C Journal website
- Volume:
- 124
- Issue:
- 33
- Pages:
- 18031-18044
- Publication date:
- 2020-07-24
- Acceptance date:
- 2020-07-22
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
1121014
- Local pid:
- pubs:1121014
- Deposit date:
- 2020-07-25
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2020
- Rights statement:
- Copyright © 2020 American Chemical Society
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: https://doi.org/10.1021/acs.jpcc.0c03791
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