Journal article
Voltammetry using multiple cycles: Porous electrodes
- Abstract:
- Simulations are reported for the cyclic voltammetry of both electrochemically reversible and irreversible one-electron processes at porous electrodes where the potential cycle is applied for multiple cycles. It is shown that an ‘ultimate state’ is approached asymptotically and that the long time voltammogram can be very different in terms of the peak height from those recorded in the first scan though peak-to-peak potential separations are conserved. The implications for the experimental study of porous electrodes are considered.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Preview, Accepted manuscript, pdf, 1008.7KB, Terms of use)
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(Preview, Accepted manuscript, pdf, 1.1MB, Terms of use)
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- Publisher copy:
- 10.1016/j.jelechem.2017.05.043
Authors
- Publisher:
- Elsevier
- Journal:
- Journal of Electroanalytical Chemistry More from this journal
- Volume:
- 799
- Pages:
- 126-133
- Publication date:
- 2017-05-25
- Acceptance date:
- 2017-05-23
- DOI:
- EISSN:
-
1572-6657
- ISSN:
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1873-2569
- Keywords:
- Pubs id:
-
pubs:701991
- UUID:
-
uuid:a2d5cf4b-1669-4c54-a0f7-0ae2a0b533c3
- Local pid:
-
pubs:701991
- Source identifiers:
-
701991
- Deposit date:
-
2017-06-27
Terms of use
- Copyright holder:
- Elsevier BV
- Copyright date:
- 2017
- Notes:
- Copyright © 2017 Elsevier B.V. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.jelechem.2017.05.043
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