- Abstract:
-
In the search for alternative non-metabolizable inducers in the L-rhamnose promoter system, the synthesis of fifteen 6-deoxyhexoses from L-rhamnose demonstrates the value of synergy between biotechnology and chemistry. The readily available 2,3-acetonide of rhamnonolactone allows inversion of configuration at C4 and/or C5 of rhamnose to give 6-deoxy-D-allose, 6-deoxy-D-gulose and 6-deoxy-L-talose. Highly crystalline 3,5-benzylidene rhamnonolactone gives easy access to L-quinovose [6-deoxy-L-g...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted manuscript
- Files:
-
-
(pdf, 1.4mb)
-
- Publisher copy:
- 10.1002/chem.201602482
-
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- Publisher:
- Wiley Publisher's website
- Journal:
- Chemistry - A European Journal Journal website
- Volume:
- 22
- Issue:
- 35
- Pages:
- 12557–12565
- Publication date:
- 2016-07-05
- Acceptance date:
- 2016-06-21
- DOI:
- URN:
-
uuid:9a03fc97-01ae-4c72-af6a-9393e5116b48
- Source identifiers:
-
631798
- Local pid:
- pubs:631798
- Copyright holder:
- WILEY-VCH Verlag GmbH and Co
- Copyright date:
- 2016
- Notes:
- © 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim
Journal article
6-deoxyhexoses from L-rhamnose in the search for inducers of the rhamnose operon: Synergy of chemistry and biotechnology
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