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An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation

Abstract:
Oxidation and stress corrosion cracking (SCC) of 316L stainless steel were studied in simulated pressurized water reactor primary water. Surface, crack flank, and crack tip oxides were analyzed and compared by high-resolution characterization, including oxidation state mapping. All oxides were found to have a triplex structure, although of different dimensions and composition, revealing the effects of local water chemistry and applied stress. The higher oxidation rate at the crack tip could be explained due to the existence of a higher dislocation density, higher level of stress and cation unavailability from the environment. The implications to SCC mechanisms are discussed.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.corsci.2018.12.020

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
ORCID:
0000-0003-3387-5973


Publisher:
Elsevier
Journal:
Corrosion Science More from this journal
Volume:
148
Pages:
213-227
Publication date:
2018-12-25
Acceptance date:
2018-12-14
DOI:
EISSN:
1879-0496
ISSN:
0010-938X


Language:
English
Keywords:
Pubs id:
pubs:956246
UUID:
uuid:927b6241-5f15-42e4-b4a9-1d999409f86c
Local pid:
pubs:956246
Source identifiers:
956246
Deposit date:
2019-01-14
ARK identifier:

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