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Cyclic voltammetry with non-triangular waveforms: Electrochemically reversible systems

Abstract:

Cyclic voltammetry is typically performed using triangular waveforms, however, complications inevitably arise from the discontinuous nature of the differentiated triangular wave: As the capacitive current contributions are proportional to the derivative of the applied electrode potential, the measured current is (at least theoretically) discontinuous, which experimentally manifests in perturbed voltammetric data following minima and maxima in the applied triangular wave that is mostly due to ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.jelechem.2017.08.008

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Institution:
University of Oxford
Oxford college:
Keble College
Role:
Author
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Name:
European Research Council
Grant:
320403
Publisher:
Elsevier
Journal:
Journal of Electroanalytical Chemistry More from this journal
Volume:
801
Pages:
381-387
Publication date:
2017-08-09
Acceptance date:
2017-08-03
DOI:
ISSN:
1572-6657
Keywords:
Pubs id:
pubs:723995
UUID:
uuid:8e843dd7-4512-42c3-9c4a-906a72730ac4
Local pid:
pubs:723995
Source identifiers:
723995
Deposit date:
2017-09-04

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