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Synthesis and characterization of mixed-metal germanates

Abstract:

Mixed-metal germanates with the general formula ABB’Ge4O12 have been synthesised using the ceramic method and their properties characterised by X-ray diffraction, neutron diffraction, dc and ac magnetometry, specific heat and Mossbauer spectroscopy. DFT calculations were conducted on two compounds ZrM2Ge4O12 (M = Mn, Co). All compositions adopt a tetragonal structure (space group P4/nbm with the unit-cell parameters a = b ~ 2c). The ca...

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Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author

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Supervisor
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Examiner
Role:
Examiner

Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

UUID:
uuid:8a6b4ca2-0824-4d9a-8907-b40537405c72
Deposit date:
2018-03-16

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