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Synthesis and characterization of mixed-metal germanates

Abstract:

Mixed-metal germanates with the general formula ABB’Ge4O12 have been synthesised using the ceramic method and their properties characterised by X-ray diffraction, neutron diffraction, dc and ac magnetometry, specific heat and Mossbauer spectroscopy. DFT calculations were conducted on two compounds ZrM2Ge4O12 (M = Mn, Co). All compositions adopt a tetragonal structure (space group P4/nbm with the unit-cell parameters a = b ~ 2c). The ca...

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Role:
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Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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