Thesis
Studies of rotational isomerism
- Abstract:
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Because the measured thermodynamic properties of ethane did not agree with those calculated from statistical mechanics, Pitzer proposed the existence of energy barriers hindering internal rotation about single bonds. A consequence of hindered rotation is that molecules may exist in more than one stable conformation: these conformations are referred to as "rotational isomers". Depending on the magnitude of the energy barrier relative to thermal energy, the conformers (or rotamers) may be in...
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- Peer review status:
- Peer reviewed
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(pdf, 10.8MB)
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Authors
Bibliographic Details
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
- Source identifiers:
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6018707871
Item Description
- UUID:
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uuid:8996cb69-c25e-4d4b-900c-7bc9045f4a74
- Local pid:
- polonsky:14:27
- Deposit date:
- 2017-10-05
Terms of use
- Copyright holder:
- Chadwick, D; Chadwick, D J
- Copyright date:
- 1972
- Notes:
- This thesis was digitised thanks to the generosity of Dr Leonard Polonsky
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