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Thesis

Studies of some volatile compounds of main group elements

Abstract:

Methylzinc tetrahydroborate, [MeZnBH4], has been prepared by two routes and the structure of the solid determined by X-ray crystallography to reveal helical polymers in which MeZn and BH4 units alternate. The latter functions as a bidentate ligand with respect to each of the adjacent metal atoms. Investigation by mass spectrometry and matrix isolation shows that the vapour consists of an equilibrium mixture of monomeric and dimeric species. The pattern of infrared ba...

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Institution:
University of Oxford
Department:
Mathematical and Physical Sciences Division

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Role:
Supervisor
Publication date:
1996
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Barcode:
602801769
URN:
uuid:832a8ba8-4b6f-45f3-8a23-403efa9cd6e1
Local pid:
td:602801769
Language:
English
Subjects:

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