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Studies of elementary reactions of interest in hydrocarbon pyrolysis

Abstract:

A novel hydrogen atom source, involving the 193.3 nm photolysis of nitrous oxide in the presence of hydrogen, is described. The system is shown to provide a very clean source of hydrogen atoms, particularly at temperatures above 400K. The H + C2H4 addition reaction is studied as a function of pressure (50-750 Torr He) and temperature (285-604K). Resonance fluorescence was used to monitor hydrogen atom concentrations in real time, following excimer (ArF) photolysis of...

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Institution:
University of Oxford
Department:
Mathematical and Physical Sciences Division

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Role:
Supervisor
Role:
Supervisor
Publication date:
1986
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Barcode:
603083758
URN:
uuid:78fb871e-ac5c-471e-9558-3e72171a42d1
Local pid:
td:603083758
Language:
English
Subjects:

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