Structure-property relations in superalloy single crystals

Thesis



This research is concerned with a single crystal nickel-base superalloy which has been developed for application as a high pressure turbine blade material in jet aircraft engines. The microstructures and mechanical properties of superalloys, including the effects of heat-treatments, have been reviewed.

The effects of heat-treatments on the γ' precipitate distributions have been investigated. During ageing at 900°C or 800°C, the precipitates adopt an irregular, rounded and highly interconnected microstructure, indicative of precipitate coalescence, whilst at higher ageing temperatures a regular cuboidal precipitate morphology is formed. The kinetics of precipitate coarsening have been investigated, and slight deviations from the power-law predicted by a number of theoretical models were observed. These deviations have been discussed in terms of a progressive transition in the dominant coarsening mechanism.

Constant load creep tests were carried out, and although the tensile axis was nominally parallel to [001], the degree and direction of misorientation were found to be critical to the extent of the primary creep strain. Primary creep was shown to proceed by slip on a single (111)[112] system, until the activation of intersecting slip systems brings about the onset of the secondary creep stage. The extent of primary creep has been shown to be reduced by application of a final ageing treatment at 870°C.

Precipitate shear by paired dislocations in intense slip bands occurs during high strain-rate deformation at both ambient temperature and at 750°C. Application of a final ageing treatment at 870°C was found to increase the 0.2% proof stress and to bring about the activation of an alternative mode of precipitate shear by dissociated dislocations. The 870°C ageing treatment was shown to cause slight chemical changes at the γ/γ' interfaces, and these are believed to have caused the observed changes in mechanical properties.

Authors: Hopgood, A

• Publication date: 1984
• Type of award: DPhil
• Level of award: Doctoral
• Awarding institution: University of Oxford
• Language: English
• Subjects: Turbines; Jet transports; Blades; Heat resistant alloys