Thesis
Azo-anions in organic synthesis
- Abstract:
-
Novel synthetic applications of ambident azo-anions derived from hindered hydrazones have been investigated. Reaction with electrophiles occurred predominantly at carbon as the N-addition pathway was sterically retarded. Trityl, diphenyl-4-pyridylmethyl (DPP) benzhydryl, and t-butyldiphenylmethyl (BDP) hydrazones of various aldehydes and ketones were prepared in good yields from the corresponding hydrazines and carbonyls in aqueous methanol. The lithium salts derived from trityl and DPP h...
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Bibliographic Details
- Publication date:
- 1985
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
Item Description
- Language:
- English
- Subjects:
- UUID:
-
uuid:690ab891-be13-4582-a029-47974d20adac
- Local pid:
- td:602800556
- Source identifiers:
-
602800556
- Deposit date:
- 2014-04-01
Terms of use
- Copyright holder:
- I. M. Newington
- Copyright date:
- 1985
- Notes:
- This thesis was digitised thanks to the generosity of Dr Leonard Polonsky.
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