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A new phosphoramidite enables orthogonal double labelling to form combination oligonucleotide probes

Abstract:
Oligonucleotides labelled with thiazole orange intercalator and a reporter dye on the same thymine base have been synthesized. The key phosphoramidite (AP-C3 dT) contains an alkyne and amine, enabling dual orthogonal labelling of the nucleobase. Multiple monomers can be added to produce heavily functionalised oligonucleotides. In their DNA and 2′-OMe RNA formats these combination probes display high duplex stability and fluorescence when bound to complementary DNA and RNA
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d2ob01899c

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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-4150-8201
More by this author
Institution:
University of Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-0430-703X
More by this author
Institution:
University of Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Role:
Author
ORCID:
0000-0001-8706-1292


Publisher:
Royal Society of Chemistry
Journal:
Organic & Biomolecular Chemistry More from this journal
Volume:
20
Issue:
44
Pages:
8618-8622
Publication date:
2022-11-16
DOI:
EISSN:
1477-0539
ISSN:
1477-0520


Language:
English
Keywords:
Pubs id:
1301201
Local pid:
pubs:1301201
Source identifiers:
W4307777289
Deposit date:
2026-04-29
ARK identifier:
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