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Snap-shots of cluster growth: structure and properties of a Zintl ion with an Fe<sub>3</sub> core, [Fe<sub>3</sub>Sn<sub>18</sub>]<sup>4−</sup>

Abstract:
The effective oxidation state of the Sn 18 unit determines the degree of fusion of the two Sn 9 polyhedra in the series [Ni 2 CdSn 18 ] 6− , [Fe 3 Sn 18 ] 4− and [Pd 2 Sn 18 ] 4− . The new [Fe 3 Sn 18 ] 4− cluster represents an intermediate phase in the fusion process.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d3sc04709a

Authors

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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0001-9647-8807
More by this author
Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-8991-1921


More from this funder
Funder identifier:
10.13039/501100013314
Grant:
B18030
More from this funder
Funder identifier:
10.13039/501100006606
Grant:
21JCZXJC00140
More from this funder
Funder identifier:
10.13039/501100001809
Grant:
92161102


Publisher:
Royal Society of Chemistry
Journal:
Chemical Science More from this journal
Volume:
15
Issue:
3
Pages:
1018-1026
Publication date:
2023-12-02
DOI:
EISSN:
2041-6539
ISSN:
2041-6520


Language:
English
Keywords:
Pubs id:
1598737
Local pid:
pubs:1598737
Source identifiers:
W4389266119
Deposit date:
2026-06-05
ARK identifier:
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