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Thesis

From polymers to rings and back again: catalytic recycling of waste oxygenated polymers

Abstract:
This thesis describes the chemical recycling to monomer of polycarbonates and polyesters. In particular, this thesis investigates different catalysts for the chemical recycling of CO2-derived polycarbonates and develops a new chemical recycling route for epoxide/anhydride derived polyesters. The chemical recycling of poly(L-lactide) blends to L-lactide is also explored. The poly(L-lactide) chemical recycling process is then evaluated by techno-economic analysis and life cycle assessment. This thesis explores the scale up of the poly(L-lactide) to L-lactide chemical recycling process and compares the economic and environmental impacts of the chemical recycling process to virgin polymer production.

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Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Research group:
Williams group
Oxford college:
Christ Church
Role:
Author

Contributors

Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Examiner
ORCID:
0000-0002-6833-5574
Role:
Examiner


More from this funder
Funder identifier:
https://ror.org/0439y7842
Grant:
EP/Z532782/1
Programme:
Sustainable Chemicals and Materials Manufacturing Hub SCHEMA
More from this funder
Funder identifier:
https://ror.org/0439y7842
Grant:
EP/S023828/1
Programme:
Oxford Inorganic Chemistry for Future Manufacturing Centre for Doctoral Training (OxICFM CDT)


DOI:
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford


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