- Abstract:
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This thesis describes efforts to develop new methods for the synthesis of bridged azacycles using nitrogen-directed free radical rearrangements. Free radical addition to 7-azanorbornadienes were carried out to give 7-substituted 2- azanorbornenes (Scheme a.l, X-Y = RS-H or PhSe-H).
[illustration in text ...]
Scheme a. 1 Nitrogen-directed homoallylic radical rearrangement via intermolecular radical addition.
A conceptually novel and theoretically interesting n...
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- Publication date:
- 2002
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
- URN:
-
uuid:316d2379-4019-4361-937d-ff1e064f8bb9
- Local pid:
- td:602835567
- Language:
- English
- Subjects:
- Copyright holder:
- Bebbington, M. W. P.
- Copyright date:
- 2002
- Notes:
- The digital copy of this thesis has been made available thanks to the generosity of Dr Leonard Polonsky
Thesis
Nitrogen-directed free radical rearrangements
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