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Thesis

Nitrogen-directed free radical rearrangements

Abstract:

This thesis describes efforts to develop new methods for the synthesis of bridged azacycles using nitrogen-directed free radical rearrangements. Free radical addition to 7-azanorbornadienes were carried out to give 7-substituted 2- azanorbornenes (Scheme a.l, X-Y = RS-H or PhSe-H).

[illustration in text ...]

Scheme a. 1 Nitrogen-directed homoallylic radical rearrangement via intermolecular radical addition.

A conceptually novel and theoretically interesting n...

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Institution:
University of Oxford
Department:
Mathematical and Physical Sciences Division

Contributors

Role:
Supervisor
Publication date:
2002
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Barcode:
602835567
URN:
uuid:316d2379-4019-4361-937d-ff1e064f8bb9
Local pid:
td:602835567
Language:
English
Subjects:

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