This thesis describes efforts to develop new methods for the synthesis of bridged azacycles using nitrogen-directed free radical rearrangements. Free radical addition to 7-azanorbornadienes were carried out to give 7-substituted 2- azanorbornenes (Scheme a.l, X-Y = RS-H or PhSe-H).
[illustration in text ...]
Scheme a. 1 Nitrogen-directed homoallylic radical rearrangement via intermolecular radical addition.
A conceptually novel and theoretically interesting n...Expand abstract
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- University of Oxford
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- Bebbington, M. W. P.
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- The digital copy of this thesis has been made available thanks to the generosity of Dr Leonard Polonsky
Nitrogen-directed free radical rearrangements
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