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Thesis

Development and mechanistic investigations into metal-catalysed cycloisomerisation of enynamides

Abstract:

This thesis reports the work on investigations into the mechanism of palladium-catalysed enynamide cycloisomerisations (with Pd(OAc)2 / bis(benzylidene)ethylenediamine (bbeda) catalyst system in particular). Herein, it has been shown that the mechanism of this catalyst system is likely to proceed via a hydropalladation mechanism. In the course of study, we have uncovered the crucial influences of water, the pre-catalyst, and the ligand (bbeda) in this reaction. One of the key highlights is...

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Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Department:
University of Oxford
Role:
Author

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Role:
Supervisor
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
UUID:
uuid:21aa7178-f12b-40ed-b738-4f7809f63f33
Deposit date:
2018-02-15

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