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Thesis

Synthesis and use of new chiral DABCO derivatives for asymmetric fluorination

Abstract:

In this thesis, the synthesis, reactivity and enantioselectivity of novel chiral Selectfluor Analogues were investigated.

Chapter 1: Discussed is a general introduction to Selectfluor as an achiral electrophilic fluorinating reagent and its role as an oxidant in a wide variety of transformations and summarises the aims and objectives of the project.

Chapter 2: The synthesis of chiral 2-monosubstituted, 2,3-disusbstituted and 2,5-disubstituted DABCO derivatives is described. We ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Research group:
Gouverneur group
Oxford college:
Wolfson College
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
More from this funder
Name:
Engineering and Physical Sciences Research Council
Funding agency for:
Ilupeju, JO
Publication date:
2012
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
UUID:
uuid:1ee07d47-49ce-4072-a739-c20857d3b468
Local pid:
ora:7583
Deposit date:
2013-11-15

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