- Abstract:
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Transition Metal Catalyzed Alkylation
We have reported methodology for the use of methanol as an alkylation reagent using catalytic rhodium or iridium species for the formation of branched products from methyl ketones. The synthetic utility of the dialkylated products was enhanced by performing a regioselective Baeyer-Villiger oxidation which allowed access to ester products. A range of different phosphine ligands were screened, and sterically hindered and electron rich phosp...
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- Publication date:
- 2014
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- Oxford University, UK
- URN:
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uuid:1467ba98-846c-46e6-9620-e4639ed07e43
- Local pid:
- ora:11308
- Language:
- English
- Keywords:
- Subjects:
- Copyright holder:
- Di Shen
- Copyright date:
- 2014
Thesis
Transition metal catalyzed alkylation and synthesis of biotin derivatives
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