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Ligand design and mechanism in hydroformylation

Abstract:

In this work the synthesis of new potentially trans-chelating biphosphine ligands is described and their value in rhodium catalysed hydroformylation evaluated. The reactions of biphosphine diolefin rhodium complexes with hydrogen in methanol, monitored by 1H- and 31P-NMR spectroscopy were used to determine trans-chelating ability. Complexes of 1,5-bis(diphenylphosphino)-3-oxapentane and 1,3-bis- (4-diphenylphosphinobenzyl)benzene f...

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Institution:
University of Oxford
Department:
Mathematical and Physical Sciences Division

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Role:
Supervisor
Role:
Supervisor
Publication date:
1981
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Barcode:
603839203
URN:
uuid:09b5ed6e-af79-4565-aacf-713e8657d6da
Local pid:
td:603839203
Language:
English
Subjects:

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