Thesis
Ligand design and mechanism in hydroformylation
- Abstract:
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In this work the synthesis of new potentially trans-chelating biphosphine ligands is described and their value in rhodium catalysed hydroformylation evaluated. The reactions of biphosphine diolefin rhodium complexes with hydrogen in methanol, monitored by 1H- and 31P-NMR spectroscopy were used to determine trans-chelating ability. Complexes of 1,5-bis(diphenylphosphino)-3-oxapentane and 1,3-bis- (4-diphenylphosphinobenzyl)benzene f...
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Bibliographic Details
- Publication date:
- 1981
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
- Source identifiers:
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603839203
Item Description
- Language:
- English
- Subjects:
- UUID:
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uuid:09b5ed6e-af79-4565-aacf-713e8657d6da
- Local pid:
- td:603839203
- Deposit date:
- 2013-06-22
Terms of use
- Copyright holder:
- Kent, A
- Copyright date:
- 1981
- Notes:
- The digital copy of this thesis has been made available thanks to the generosity of Dr Leonard Polonsky
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