Thesis
Inhibition of [NiFe]-hydrogenases with pi-acid ligands: electrochemical and in situ infrared spectroelectrochemical studies
- Abstract:
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Hydrogenases are of great interest because they utilise abundant and inexpensive metals, Fe or Ni-Fe, in their active sites to catalyse hydrogen cycling – highly relevant to enzyme-based or bio-inspired technologies. The Fe in the active site is in a biologically unusual ligand environment coordinated by CO and CN-. These small molecule ligands have intense infrared absorption features and serve as good probes to monitor the coordination state and electronic environment of the active site....
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Bibliographic Details
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
Item Description
- UUID:
-
uuid:03779d7b-565c-448d-a877-9da46218b56d
- Deposit date:
- 2016-02-15
Terms of use
- Copyright holder:
- Chung, M
- Copyright date:
- 2016
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