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Antibacterial mimics of natural products by side-chain functionalization of bicyclic tetramic acids

Abstract:

Tetramic acids with unsaturated acyl chains are widely found in natural products possessing a range of biological activities, and bicyclic tetramates represent a suitable scaffold to prepare simple mimics of such complex molecules. An efficient route to functionalize the C(6)-acyl group of a bicyclic tetramate was developed and utilized to prepare a small chemical library with a range of saturated and unsaturated side-chains. The analogues with lipophilic residues possessed highly potent anti...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.joc.8b01453

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
St Peter's College
Role:
Author
ORCID:
0000-0002-4440-3632
More from this funder
Funding agency for:
Josa-Cullere, L
Grant:
People Programme (Marie Curie Actions) 316955
Publisher:
American Chemical Society
Journal:
Journal of Organic Chemistry More from this journal
Volume:
83
Issue:
17
Pages:
10303–10317
Publication date:
2018-07-20
Acceptance date:
2018-07-20
DOI:
EISSN:
1520-6904
ISSN:
0022-3263
Pmid:
30028145
Language:
English
Pubs id:
pubs:891119
UUID:
uuid:ff337d61-f9a6-4d23-be9c-ef659cdf65f0
Local pid:
pubs:891119
Source identifiers:
891119
Deposit date:
2018-08-10

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