- Abstract:
-
We report the low-frequency resonant Raman spectrum of methylammonium lead-iodide, a prototypical perovskite for solar cells applications, on mesoporous Al2O3. The measured spectrum assignment is assisted by DFT simulations of the Raman spectra of suitable periodic and model systems. The bands at 62 and 94 cm-1 are assigned respectively to the bending and to the stretching of the Pb-I bonds, and are thus diagnostic modes of the inorganic cage. We also assign the librations of the organic cati...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/jz402589q
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY LETTERS
- Volume:
- 5
- Issue:
- 2
- Pages:
- 279-284
- Publication date:
- 2014-01-16
- DOI:
- EISSN:
-
1948-7185
- ISSN:
-
1948-7185
- URN:
-
uuid:ff1a3047-3efa-4cdb-890b-77a2b0ca0bc0
- Source identifiers:
-
448377
- Local pid:
- pubs:448377
- Copyright date:
- 2014
Journal article
The Raman Spectrum of the CH(3)NH(3)Pbl(3) Hybrid Perovskite: Interplay of Theory and Experiment
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