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The electrochemical oxidation of ruthenocene in various room temperature ionic liquids

Abstract:

The electrochemical behavior of ruthenocene, RuCp2, was investigated on both a platinum microdisk electrode and a platinum macroelectrode in six different room temperature ionic liquids of varying viscosity, at a range of temperatures and concentrations. It was observed that the redox behavior of RuCp2 is not well understood in both aqueous and non-aqueous media. A process involving the one electron oxidation of RuCp2 to the [RuCp2]+ monocation, followed by dimerization to form the [Cp2Ru-RuC...

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Publication status:
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Authors


Rogers, EI More by this author
Lawrence, NS More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
657
Issue:
1-2
Pages:
144-149
Publication date:
2011-07-01
DOI:
ISSN:
1572-6657
URN:
uuid:fd0e6d41-bf78-4a41-bd7a-4f27bf7ff9be
Source identifiers:
164304
Local pid:
pubs:164304

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