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Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation

Abstract:

The development of new reactions forming asymmetric carbon–carbon bonds has enabled chemists to synthesize a broad range of important carbon-containing molecules, including pharmaceutical agents, fragrances and polymers. Most strategies to obtain enantiomerically enriched molecules rely on either generating new stereogenic centres from prochiral substrates or resolving racemic mixtures of enantiomers. An alternative strategy—dynamic kinetic asymmetric transformation—involves the transformatio...

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Publication status:
Published
Peer review status:
Peer reviewed

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More from this funder
Name:
Engineering and Physical Sciences Research Council
Publisher:
Nature Publishing Group
Journal:
Nature More from this journal
Volume:
517
Pages:
351–355
Publication date:
2015-01-14
Acceptance date:
2014-11-13
DOI:
EISSN:
1476-4687
ISSN:
0028-0836
UUID:
uuid:fc74803e-bcfd-4cdb-a6ac-658f519a751d
Deposit date:
2015-09-18

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