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Journal article

High charge carrier mobility in porphyrin nanoribbons

Abstract:
Polydisperse edge-fused nickel(II) porphyrin nanoribbons have been synthesized by Yamamoto coupling followed by gold(III)-mediated fusion, with average degrees of polymerization of up to 37 repeat units (length 31 nm). Time-resolved optical-pump terahertz spectroscopy measurements indicate that photo-generated charge carriers have dc mobilities of up to 205 cm2 V-1 s-1 in these nanoribbons, exceeding the values previously reported for most other types of nanoribbon or π-conjugated polymer.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.202417429

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
ORCID:
0000-0003-3240-1418
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Role:
Author
ORCID:
0009-0002-1198-2110
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Role:
Author
ORCID:
0000-0002-0090-614X
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
ORCID:
0000-0001-8866-1935
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
ORCID:
0000-0003-3799-0485


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Funder identifier:
https://ror.org/0472cxd90
Grant:
885606, ARO-MAT


Publisher:
Wiley
Journal:
Angewandte Chemie International Edition More from this journal
Volume:
64
Issue:
6
Article number:
e202417429
Place of publication:
Germany
Publication date:
2024-11-28
Acceptance date:
2024-10-20
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
39532665


Language:
English
Keywords:
Pubs id:
2062882
Local pid:
pubs:2062882
Deposit date:
2025-05-26
ARK identifier:

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