Journal article

The simulation of differential pulse voltammetry

Abstract:: The differential pulse voltammetry (DPV) experiment has been simulated using the backwards implicit finite difference approach. Results are reported for the general case of a one-electron redox transfer process at a planar electrode in stationary solution with a semiinfinite diffusion layer and are in excellent agreement with those predicted by an analytical approach, confirming the validity of the finite difference simulation. In addition, concentration profiles are presented and the effect of diffusion layer thickness on the voltammetric response quantified with experimental considerations indicated, suggesting an extension of this simulation to cover DPV at hydrodynamic electrodes.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Share
Cite

Cite this record

APA Style

Melville, J., & Compton, R. (2001). The simulation of differential pulse voltammetry. ELECTROANALYSIS, 13(2), 123–130.

MLA Style

Melville, J, and R Compton. “The Simulation of Differential Pulse Voltammetry.” ELECTROANALYSIS, vol. 13, no. 2, 2001, pp. 123–30.

Chicago Style

Melville, J, and R Compton. 2001. “The Simulation of Differential Pulse Voltammetry.” ELECTROANALYSIS 13 (2): 123–30.
Print

Access Document

Publisher copy:: 10.1002/1521-4109(200102)13:2<123::AID-ELAN123>3.3.CO;2-Q

Authors

+ Melville, J More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: ELECTROANALYSIS More from this journal
Volume:: 13
Issue:: 2
Pages:: 123-130
Publication date:: 2001-02-01
DOI:: 10.1002/1521-4109(200102)13:2<123::AID-ELAN123>3.3.CO;2-Q
ISSN:: 1040-0397

Language:: English
Keywords:: finite difference

differential pulse voltammetry

simulation
Pubs id:: pubs:37705
UUID:: uuid:faee944d-44cf-4135-ab68-4b26ae02f18a
Local pid:: pubs:37705
Source identifiers:: 37705
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_faee944d44cf4135ab684b26ae02f18a

Terms of use

Copyright date:: 2001

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP