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Kinetic and thermodynamic parameters of the Li/Li+ couple in the room temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide in the temperature range 298-318 K: a theoretical and experimental study using Pt and Ni electrodes.

Abstract:

The Li/Li+ couple is investigated in the room temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C4mpyrr][NTf2], at a range of temperatures varying from 298 to 318 K.Experiments are conducted using both nickel and platinum microelectrodes. On nickel, a single stripping peak is observed for the stripping of bulk lithium that allowed thermodynamic and kinetic parameters to be extracted via computational simulation. At 298 K, the electrochemical rate const...

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Publication status:
Published

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Publisher copy:
10.1021/jp906128t

Authors


Ward Jones, SE More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
The journal of physical chemistry. B
Volume:
113
Issue:
36
Pages:
12293-12298
Publication date:
2009-09-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:fabca5f6-6932-4076-bf4e-a72605c1a8b9
Source identifiers:
34868
Local pid:
pubs:34868
Language:
English

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