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Characterisation and application of a novel cell for mechanistic electrochemistry at elevated temperatures

Abstract:

A novel high temperature cell capable of measuring electrochemical signals up to temperatures of 115°C is reported. Characterisation of the cell has been undertaken by examining three differing systems. First the voltammetric response of a range of simple redox systems in both aqueous and non-aqueous media was recorded in order to deduce the activation energies for diffusion of these molecules. Next the steady state linear sweep voltammetric response of N,N,N′,N′-tetramethyl-p-phenylenediamin...

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Publication status:
Published

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Publisher copy:
10.1039/b307900g

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Journal:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume:
5
Issue:
19
Pages:
4219-4225
Publication date:
2003-10-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:f9e3103b-9279-4224-9884-9451606cdd82
Source identifiers:
38822
Local pid:
pubs:38822
Language:
English

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