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Theoretical analysis of the two-electron transfer reaction and experimental studies with surface-confined cytochrome c peroxidase using large-amplitude Fourier transformed AC voltammetry.

Abstract:

A detailed analysis of the cooperative two-electron transfer of surface-confined cytochrome c peroxidase (CcP) in contact with pH 6.0 phosphate buffer solution has been undertaken. This investigation is prompted by the prospect of achieving a richer understanding of this biologically important system via the employment of kinetically sensitive, but background devoid, higher harmonic components available in the large-amplitude Fourier transform ac voltammetric method. Data obtained from the co...

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Publication status:
Published

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Publisher copy:
10.1021/la205037e

Authors


Stevenson, GP More by this author
Kennedy, GF More by this author
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Journal:
Langmuir : the ACS journal of surfaces and colloids
Volume:
28
Issue:
25
Pages:
9864-9877
Publication date:
2012-06-05
DOI:
EISSN:
1520-5827
ISSN:
0743-7463
URN:
uuid:f86c0110-3e6c-49fa-b648-993b68f4dd10
Source identifiers:
332812
Local pid:
pubs:332812

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