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The Pentynoate Ligand as a Building Block for Multimetallic Systems

Abstract:

The complexes [RuRCl(CO)(BTD)(PPh3)2] (R = CH=CHtBu, CH=CHC6H4Me-4, CH=CHC5H4FeC 5H5; BTD = 2,1,3-benzothiadiazole) and [Ru{C(C≡CPh)=CHPh}(CO)(PPh3)2] reacted with pentynoic acid to yield the same complex, [RuCl(O2CCH 2CH2C≡CH)(CO)(PPh3)2], through cleavage of the vinyl ligand. In contrast, the products [RuR(O 2CCH2CH2C≡CH)(CO)(PPh3) 2] were formed when NaO2CCH2CH 2C≡CH was used. An osmium example, [Os(CH=CHC6H 4Me-4)(O2CCH2CH2C≡CH)(CO) (PPh3)2], was also prepared from treatment of [Os(CH=CHC...

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Publication status:
Published

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Publisher copy:
10.1002/ejic.201301504

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Publisher:
Wiley-VCH Verlag
Journal:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume:
2014
Issue:
12
Pages:
2065-2072
Publication date:
2014-04-05
DOI:
EISSN:
1099-0682
ISSN:
1434-1948
URN:
uuid:f85b718f-0413-40ed-b132-b21ff5c91e02
Source identifiers:
464924
Local pid:
pubs:464924

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