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Magnetic behaviour of layered Ag(II) fluorides.

Abstract:

Fluoride phases that contain the spin-1/2 4d9 Ag(II) ion have recently been predicted to have interesting or unusual magnetochemistry, owing to their structural similarity to the 3d9 Cu(II) cuprates and the covalence associated with this unusual oxidation state of silver. Here we present a comprehensive study of structure and magnetism in the layered Ag(II) fluoride Cs2AgF4, using magnetic susceptometry, inelastic neutron scattering techniques and both X-ray and neutron powder diffraction. We...

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Publication status:
Published

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Publisher copy:
10.1038/nmat1670

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Journal:
Nature materials
Volume:
5
Issue:
7
Pages:
561-566
Publication date:
2006-07-05
DOI:
EISSN:
1476-4660
ISSN:
1476-1122
URN:
uuid:f8586696-1bde-477b-8675-ca1bd7cfbc9e
Source identifiers:
196826
Local pid:
pubs:196826
Language:
English

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