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Structure and hydration of L-proline in aqueous solutions.

Abstract:

The structure and hydration of L-proline in aqueous solution have been investigated using a combination of neutron diffraction with isotopic substitution, empirical potential structure refinement modeling, and small-angle neutron scattering at three concentrations, 1:10, 1:15, and 1:20 proline/water mole ratios. In each solution the carboxylate oxygen atoms from proline accept less than two hydrogen bonds from the surrounding water solvent and the amine hydrogen atoms donate less than one hyd...

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Publication status:
Published

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Publisher copy:
10.1021/jp068340f

Authors


McLain, SE More by this author
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Institution:
University of Oxford
Department:
Oxford, MSD, Biochemistry
Journal:
The journal of physical chemistry. B
Volume:
111
Issue:
17
Pages:
4568-4580
Publication date:
2007-05-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:f8450801-ed86-43ef-bdb2-96050a66a1e1
Source identifiers:
100834
Local pid:
pubs:100834

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