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Structure and hydration of L-proline in aqueous solutions.

Abstract:

The structure and hydration of L-proline in aqueous solution have been investigated using a combination of neutron diffraction with isotopic substitution, empirical potential structure refinement modeling, and small-angle neutron scattering at three concentrations, 1:10, 1:15, and 1:20 proline/water mole ratios. In each solution the carboxylate oxygen atoms from proline accept less than two hydrogen bonds from the surrounding water solvent and the amine hydrogen atoms donate less than one hyd...

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Publication status:
Published

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Publisher copy:
10.1021/jp068340f

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Institution:
University of Oxford
Division:
MSD
Department:
Biochemistry
Role:
Author
Journal:
journal of physical chemistry. B
Volume:
111
Issue:
17
Pages:
4568-4580
Publication date:
2007-05-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Source identifiers:
100834
Language:
English
Keywords:
Pubs id:
pubs:100834
UUID:
uuid:f8450801-ed86-43ef-bdb2-96050a66a1e1
Local pid:
pubs:100834
Deposit date:
2012-12-19

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