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The electrochemical detection of arsenic(III) at a silver electrode

Abstract:

A study of three electrode substrates namely gold, platinum and silver, for arsenic detection via anodic stripping voltammetry is reported. Hitherto it has been accepted that gold is the most suitable metallic surface for use in this context, as suggested by Forsberg and co-workers (Forsberg, G.; O'Laughlin, J. W.; Megargle, R. G. Anal. Chem. 1975, 47, 1586.). We revisit these experiments and find that by switching from hydrochloric acid to nitric acid the oxidation of silver that had previou...

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Publication status:
Published

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Publisher copy:
10.1002/elan.200503299

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
17
Issue:
19
Pages:
1727-1733
Publication date:
2005-09-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:f8151285-4dd4-40f5-912f-2c830851e44d
Source identifiers:
39718
Local pid:
pubs:39718

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