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On the structure of boron trifluoride in liquid and supercritical phase investigated with neutron diffraction

Abstract:
Neutron diffraction analysis was used to study the structure of boron trifluoride in liquid and supercritical phase. Liquid BF3 displays order only in the first coordination sphere around the average molecule and there was no intermediate range order. The angular analysis using reverse Monte Carlo modeling showed that the dominant structural motif in the solid state was partially retained in both the liquid and supercritical phase.
Publication status:
Published

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Publisher copy:
10.1063/1.1604382
Journal:
JOURNAL OF CHEMICAL PHYSICS More from this journal
Volume:
119
Issue:
13
Pages:
6671-6679
Publication date:
2003-10-01
DOI:
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:196837
UUID:
uuid:f8150c6a-f8b3-47b1-a246-879797517ec7
Local pid:
pubs:196837
Source identifiers:
196837
Deposit date:
2013-11-16

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