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A Surface-Specific Isotope Effect in Mixtures of Light and Heavy Water

Abstract:

Isotope fractionation between different phases is a subtle but very important phenomenon that is related to the quantum nature of light nuclei, and that has important consequences for geochemistry, hydrology, and biology. Here we present a joint experimental/theoretical investigation of the differential segregation of hydrogen and deuterium at the liquid/vapor interface of mixtures of light and heavy water. We use both vibrational sum-frequency spectroscopy and path integral molecular dynamic...

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Publication status:
Published

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Publisher copy:
10.1021/jp311986m

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Journal:
JOURNAL OF PHYSICAL CHEMISTRY C More from this journal
Volume:
117
Issue:
6
Pages:
2944-2951
Publication date:
2013-02-14
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Language:
English
Pubs id:
pubs:388160
UUID:
uuid:f7e57ff2-0953-4aba-b14b-e9e3ba9fcbc9
Local pid:
pubs:388160
Source identifiers:
388160
Deposit date:
2013-11-16

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