Journal article icon

Journal article

Topochemical reactions of layered transition-metal oxides

Abstract:
Low-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical selectivity of these types of reactions to allow the preparation of desired phases in a rational manner. Using complex oxides adopting Ruddlesden-Popper type structures as examples, recent progress in the low-temperature topochemical reduction by anion de-intercalation, and oxidation by anion insertion, is reviewed. © 2014 IOP Publishing Ltd.
Publication status:
Published

Actions

  • Cite

  • Print

Access Document

Publisher copy:
10.1088/0268-1242/29/6/064010

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author

Publisher:
Institute of Physics Publishing
Journal:
SEMICONDUCTOR SCIENCE AND TECHNOLOGY More from this journal
Volume:
29
Issue:
6
Pages:
064010-064010
Publication date:
2014-06-01
DOI:
EISSN:
1361-6641
ISSN:
0268-1242

Language:
English
Keywords:
Pubs id:
pubs:466867
UUID:
uuid:f77920af-7c78-4c96-a2fc-04569f2512f8
Local pid:
pubs:466867
Source identifiers:
466867
Deposit date:
2014-06-20

Terms of use

Views and Downloads





If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP