Journal article

On the covalency of silver-fluorine bonds in compounds of silver(I), silver(II) and silver(III).

Abstract:: Unconventional covalence: For the higher silver fluorides the silver-fluorine chemical bonding is significantly covalent, in contrast to the conventional "ionic" picture most frequently used in the chemistry of inorganic fluorides. For KAgF4, an Ag(III) fluoride, the Ag(4d) states (see picture) are more within the "ligand band" (60%) than within the "metal band" (40%) reflecting significant covalency of the Ag-F bond, and an electronic band with significant hole production within the anionic F(2p) states.

Publication status:: Published

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APA Style

Grochala, W., Egdell, R., Edwards, P., Mazej, Z., & Zemva, B. (2003). On the covalency of silver-fluorine bonds in compounds of silver(I), silver(II) and silver(III). Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry, 4(9), 997–1001.

MLA Style

Grochala, W, et al. “On the Covalency of Silver-Fluorine Bonds in Compounds of Silver(I), Silver(II) and Silver(III).” Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry, vol. 4, no. 9, 2003, pp. 997–1001.

Chicago Style

Grochala, W, R Egdell, P Edwards, Z Mazej, and B Zemva. 2003. “On the Covalency of Silver-Fluorine Bonds in Compounds of Silver(I), Silver(II) and Silver(III).” Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry 4 (9): 997–1001.
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Publisher copy:: 10.1002/cphc.200300777

Authors

+ Grochala, W More by this author

Role:: Author

+ Egdell, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Edwards, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Mazej, Z More by this author

Role:: Author

+ Zemva, B More by this author

Role:: Author

Journal:: Chemphyschem : a European journal of chemical physics and physical chemistry More from this journal
Volume:: 4
Issue:: 9
Pages:: 997-1001
Publication date:: 2003-09-01
DOI:: 10.1002/cphc.200300777
EISSN:: 1439-7641
ISSN:: 1439-4235

Language:: English
Keywords:: photoelectron spectroscopy

electronic structure

silver

flourine
Pubs id:: pubs:38765
UUID:: uuid:f7695032-4c8a-4aae-bc66-a06803b67ada
Local pid:: pubs:38765
Source identifiers:: 38765
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_f76950324c8a4aaebc66a06803b67ada

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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