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Spectral and electrochemical recognition of halide anions by acyclic mononuclear ruthenium(II) bipyridyl receptor molecules

Abstract:

New acyclic mononuclear ruthenium(II) bipyridyl amide receptors containing phenolic and sterically bulky tert-butyl pendant arms have been prepared and characterised. Spectroscopic and electrochemical anion-coordination studies have shown these receptors to bind chloride, bromide and iodide anions via a combination of electrostatic attraction and favourable amide CONH and phenolic ROH hydrogen-bonding interactions. Stability constant determinations from NMR titration data and electrochemical ...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960002341

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
11
Pages:
2341-2346
Publication date:
1996-06-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:f7391cbb-a293-42c2-9141-a9291445d4be
Source identifiers:
45255
Local pid:
pubs:45255

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