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Journal article

effect of periodic modulation on the aperiodic current in linear−scan and cyclic voltammetries

Abstract:

The modulation of a ramped potential applied to a voltammetric electrode evokes two responses: a quasiperiodic 'ac' current of the same periodicity as the modulation, and a perturbation, of the underlying dc current. The latter is the subject of this article. Reasoning by analogy with an analytical result for reversible square-wave-modulated linear-potential-scan voltammetry, a sequence of credible arguments has allowed prediction of the de current for modulations of any waveform and of any a...

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Journal:
Journal of Electroanalytical Chemistry
Volume:
516
Issue:
1
Pages:
2-9
Publication date:
2001-01-01
ISSN:
00220728
URN:
uuid:f6dc299f-286d-4cb9-b9c4-ba36fac8fbd5
Local pid:
cs:4328

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