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Experimental and density functional study of Mn doped Bi₂Te₃ topological insulator

Abstract:
We present a nanoscale structural and density functional study of the Mn doped 3D topological insulator Bi2Te3. X-ray absorption near edge structure show that Mn has valency of nominally 2+. Extended x-ray absorption fine structure spectroscopy in combination with electron energy loss spectroscopy (EELS) shows that Mn is a substitutional dopant of Bi and Te and also resides in the van der Waals gap between the quintuple layers of Bi2Te3. Combination of aberration-corrected scanningtransmission electron microscopy and EELS show that Mn substitution of Te occurs in film regions with increased Mn concentration. First-principles calculations show that the Mn dopants favor octahedral sites and are ferromagnetically coupled.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.4971354

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Publisher:
American Institute of Physics
Journal:
APL Materials More from this journal
Volume:
4
Issue:
12
Pages:
126103-1
Publication date:
2016-12-01
Acceptance date:
2016-11-15
DOI:
ISSN:
2166-532X


Keywords:
Pubs id:
pubs:659709
UUID:
uuid:f6bde7d5-c0f9-43de-8506-41c08b7e9a14
Local pid:
pubs:659709
Source identifiers:
659709
Deposit date:
2016-11-15

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