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THE EMERGENCE OF PARAMAGNETISM IN TRANSITION-METAL CARBONYL CLUSTERS

Abstract:

Magnetic susceptibility and EPR measurements are reported for 21 osmium clusters containing between 3 and 40 osmium atoms and an even number of electrons. Clusters of nuclearity lower than ten are diamagnetic, having temperature-independent magnetic susceptibilities and no EPR spectra. All those having higher nuclearities (≫ 10) are paramagnetic, showing an EPR spectrum and a temperature-dependent susceptibility following Curie law behaviour. A molecular-orbital framework for understanding th...

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Publication status:
Published

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Journal:
CHEMICAL PHYSICS LETTERS More from this journal
Volume:
139
Issue:
3-4
Pages:
336-344
Publication date:
1987-08-28
DOI:
ISSN:
0009-2614
Language:
English
Pubs id:
pubs:46504
UUID:
uuid:f69bfa12-2d23-4559-b9ef-219fa3e538e1
Local pid:
pubs:46504
Source identifiers:
46504
Deposit date:
2012-12-19

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