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Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability.

Abstract:
A net change: A fully reversible ligand substitution involving coordination/ uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three-dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin-crossover transition; the compound shows magnetic and chromatic bistability (see picture).
Publication status:
Published

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Publisher copy:
10.1002/anie.200351853

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
42
Issue:
32
Pages:
3760-3762
Publication date:
2003-08-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:117223
UUID:
uuid:f55eda2e-84a5-4531-9289-5e51171131b5
Local pid:
pubs:117223
Source identifiers:
117223
Deposit date:
2012-12-19

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