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Synthesis and structure of [Fe(eta(5)-C9Me6)(eta(5)-C5H4)SiMe2]: A mixed-ring [1]ferrocenophane

Abstract:

A new bridged ligand incorporating the hexamethylindenyl moiety has been synthesized and used to prepare the corresponding ansa ferrocene, [Fe(η5-C9-Me6)(η5-C 5H4)SiMe2], 10, which is the first mixed-ring [1]ferrocenophane to be structurally characterized. Comparison of the crystal structure of 10 with those of [Fe-(η5-C5H4)2SiMe2], 1, and rac-[Fe(η5-C9Me6)2SiMe 2], 5a, shows many structural features, such as the ring tilt of 17°, to be intermediate between those of the two model compounds, w...

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Publication status:
Published

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Publisher copy:
10.1021/om980988u

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
ORGANOMETALLICS
Volume:
18
Issue:
11
Pages:
2281-2284
Publication date:
1999-05-24
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:f5455781-2f1d-4baf-b99f-0b8c51c96565
Source identifiers:
51124
Local pid:
pubs:51124
Language:
English

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