Journal article

Synthesis and structure of [Fe(eta(5)-C9Me6)(eta(5)-C5H4)SiMe2]: A mixed-ring [1]ferrocenophane

Abstract:: A new bridged ligand incorporating the hexamethylindenyl moiety has been synthesized and used to prepare the corresponding ansa ferrocene, [Fe(η5-C9-Me6)(η5-C 5H4)SiMe2], 10, which is the first mixed-ring [1]ferrocenophane to be structurally characterized. Comparison of the crystal structure of 10 with those of [Fe-(η5-C5H4)2SiMe2], 1, and rac-[Fe(η5-C9Me6)2SiMe 2], 5a, shows many structural features, such as the ring tilt of 17°, to be intermediate between those of the two model compounds, while the average Si-C(ipso) bond length is much closer to that in 5a.

Publication status:: Published

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APA Style

Tudor, J., Barlow, S., Payne, B., O'Hare, D., Nguyen, P., Evans, C., & Manners, I. (1999). Synthesis and structure of [Fe(eta(5)-C9Me6)(eta(5)-C5H4)SiMe2]: A mixed-ring [1]ferrocenophane. ORGANOMETALLICS, 18(11), 2281–2284.

MLA Style

Tudor, J, et al. “Synthesis and Structure of [Fe(Eta(5)-C9Me6)(Eta(5)-C5H4)SiMe2]: A Mixed-Ring [1]Ferrocenophane.” ORGANOMETALLICS, vol. 18, no. 11, 1999, pp. 2281–84.

Chicago Style

Tudor, J, S Barlow, B Payne, et al. 1999. “Synthesis and Structure of [Fe(Eta(5)-C9Me6)(Eta(5)-C5H4)SiMe2]: A Mixed-Ring [1]Ferrocenophane.” ORGANOMETALLICS 18 (11): 2281–84.
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Publisher copy:: 10.1021/om980988u

Authors

+ Tudor, J More by this author

Role:: Author

+ Barlow, S More by this author

Role:: Author

+ Payne, B More by this author

Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Nguyen, P More by this author

Role:: Author

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Journal:: ORGANOMETALLICS More from this journal
Volume:: 18
Issue:: 11
Pages:: 2281-2284
Publication date:: 1999-05-24
DOI:: 10.1021/om980988u
EISSN:: 1520-6041
ISSN:: 0276-7333

Language:: English
Pubs id:: pubs:51124
UUID:: uuid:f5455781-2f1d-4baf-b99f-0b8c51c96565
Local pid:: pubs:51124
Source identifiers:: 51124
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_f54557812f1d4bafb99f0b8c51c96565

Terms of use

Copyright date:: 1999

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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