- Abstract:
-
Optical resolution of the asymmetric chelating agent (±)-Ph2PCH2S(O)Me has been achieved via fractional crystallization of a pair of diastereomeric palladium(II) cationic complexes containing the sulfinyl-substituted ligand and ortho-metallated (S)-[1-(dimethylamino)ethyl]naphthalene. The X-ray structural analysis of the perchlorate salt of the less-soluble diastereomer confirmed that the sulfinyl-substituted phosphine co-ordinated to the palladium via phosphorus and oxygen with the non-co-or...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/a800510i
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 10
- Pages:
- 1639-1643
- Publication date:
- 1998-05-21
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
1472-7773
- URN:
-
uuid:f5442f98-3bb8-4978-8f8d-e38ec4d6bb70
- Source identifiers:
-
115942
- Local pid:
- pubs:115942
- Language:
- English
- Copyright date:
- 1998
Journal article
Optical resolution and the stereoelectronic properties of chelating (+/-)-[(methylsulfinyl)methyl]diphenylphosphine
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