Journal article icon

Journal article

Optical resolution and the stereoelectronic properties of chelating (+/-)-[(methylsulfinyl)methyl]diphenylphosphine

Abstract:

Optical resolution of the asymmetric chelating agent (±)-Ph2PCH2S(O)Me has been achieved via fractional crystallization of a pair of diastereomeric palladium(II) cationic complexes containing the sulfinyl-substituted ligand and ortho-metallated (S)-[1-(dimethylamino)ethyl]naphthalene. The X-ray structural analysis of the perchlorate salt of the less-soluble diastereomer confirmed that the sulfinyl-substituted phosphine co-ordinated to the palladium via phosphorus and oxygen with the non-co-or...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/a800510i

Authors


Expand authors...
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
10
Pages:
1639-1643
Publication date:
1998-05-21
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
URN:
uuid:f5442f98-3bb8-4978-8f8d-e38ec4d6bb70
Source identifiers:
115942
Local pid:
pubs:115942
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP