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Thesis

Immobilisation and application of bifunctional iminophosphorane organocatalysts

Abstract:

Bifunctional iminophosphoranes, containing a triaryl-substituted iminophosphorane and bis(3,5- trifluoromethyl)phenyl thiourea on a single enantiomer scaffold are novel asymmetric superbase organocatalysts reported by the Dixon group in 2014. This thesis describes our efforts to expand their scope and utility in a variety of challenging chemical transformations.

Chapter 2 describes the development and application of immobilised bifunctional iminophosphorane organocatalysts. We have ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author

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Role:
Supervisor
Publication date:
2014
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
Language:
English
Keywords:
Subjects:
UUID:
uuid:f4f28a47-0373-4b66-8537-d4e7028d4d63
Local pid:
ora:10605
Deposit date:
2015-03-16

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